Tissue Engineering
Reports summarize tissue engineering research from A. Furstner and co-authors
Published in Blood Weekly, January 10th, 2008
According to a study from Mulheim, Germany, "A high yielding approach to planar chiral carbene ligands is described, in which an imidazo[1,5-a]pyridine-3-ylidene unit is embedded into a cyclophane scaffold. As evident from the IR data of the corresponding rhodium complex 18 as the parent member of this family, these new ligands turned out to be exceptionally strong electron donors, rivaling or even outperforming the other diaminostabilized five-membered N-heterocyclic carbenes (NHC) known to date."
"If the remote ring of the cyclophane is substituted by four fluorine atoms, however, the donor capacity is significantly reduced by the through-space interaction of the...
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Source: Blood Weekly (2008-01-10)
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