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Organometallic Chemistry

Study results from Liaocheng University provide new insights into organometallic chemistry

Published in Cancer Weekly, October 5th, 2010

"Five 12-MC-4 organotin(IV) metallacrowns(MCs) with the types of [12-MCRSn(IV)N(shi)-4] (R - Et (1), Bu (2), Ph (3); H(3)Shi = salicylhydroxamic acid) and [12-MCRSn(IV)N(Clshi)-4] (R = Et (4), Bu (5), H(3)Clshi = 5-chlorosalicylhydroxamic acid) have been synthesized and characterized by elemental analyses, IR and TGA," scientists writing in the Journal of Organometallic Chemistry report.

"X-ray single-crystal diffraction analyses were also carried out and showed that all complexes 1-5 contain a neutral 12-membered metallacrown ring which is formed by the succession of four repeating units of -[Sn-N-O]-, indicating the substituents on the tin(IV) atom are...

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